Is it possible to purchase one license of Pro and use that single license on my work PC and my personal PC?

No.

However, you can deactivate your license from the “License” top menu and then reactivate it on another PC. You can also buy a SlideDog license with more than one activation. This allows you to have SlideDog Pro installed on your home and office PC at the same time.

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Posted in: 6. Order and Payment, 7. Pro Features